I like your question, @Jennifer Michaels - it tells me you want to give the students every advantage, and that's commendable. Let me diverge momentarily, however, and tell you one aspect of advice that I usually give to new teachers and that is also included in "Online Teaching Basics" that I prepare - Make your first quiz extra credit, about the syllabus, and make it happen first thing. Remove the anxiety about grades and allow the students to figure out the LMS and all the pop-up blocker issues that come with different browsers and configurations.
If you apply the concept to students, exposure is the key. I would encourage (require...?) students to go in and complete their profile. It's not exactly Facebook snazzy, but it would allow them to tell the world a little about themselves, and most students (ok, people in general) like writing a short autobio and uploading a picture. Any exposure you can generate will help them feel more comfortable, which also indirectly teaches them how to navigate, upload, and browse within Canvas, all before any teacher can inundate them with homework 😃
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