@amy_lautenschla So I called support just now, as I had this same question from a teacher today. What I confirmed is that a pending user will NOT receive email notifications for that course nor will they show up in a Canvas Message, if you try to message the class members.
It makes sense that they wouldn't receive notification until they are officially accepted members of a course. This is especially important for manually added people. Otherwise, you could be added to all sorts of courses without your permission or you accepting that enrollment and then begin to receive notifications and communication from that pending enrollment.
Hope that makes sense.
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