Hi @JustinBauerle,
I don't think Canvas has anything like that built in. Enrollments are generally expected to be handled by an external student information system and then synced to Canvas or done manually through the UI. I know I have seen requests like this before, but I'm not sure if anyone has tackled this issue via a custom API script that would run on a periodic schedule. That would probably be the only way to do anything like this if the enrollments can't be synced from the student information system side of things, at least the only way I can think of in my head right now aside from manually comparing the people pages and making adjustments manually.
Hope this at least gives you an answer, even if its not the one you were hoping to get. If someone else knows info that I don't, I'm sure they will respond and let you know too.
-Chris